9. Highly Efficient and Non-Precious Metal for the Li-SOCl$_{2}$ Battery Using Nitrogen Doped Carbon Supported Cu Nanoparticles (Times cited = 1)

Abstract

For lithium thionyl chloride batteries, the catalytic activity of the cathode material plays a crucial role in its electrochemical performance. In this paper, a poly (1-vinyl-3-methylimidazolium dicyanamide) ionic liquid (PIL) is selected as precursor to support CuO nanoparticles, and an efficient, non-precious metal nitrogen doped carbon supported Cu nanoparticles (N-C@Cu) composite material is designed and prepared for the lithium thionyl chloride battery cathode catalyst. X-ray diffraction (XRD) and high-resolution transmission electron microscope (HRTEM) verified that the supported CuO nanoparticles is reduced to Cu via carbon which formed from the thermally decompose of PIL. X-ray photoelectron spectroscopy (XPS) images confirm the existence of nitrogen doped carbon and Cu nanoparticles. Raman spectroscopy also demonstrate that the interaction between Cu and N-C provides more active sites. The N-C@Cu composite catalyst exhibits excellent activity in the reduction process of thionyl chloride, as can be seen from the materials display characteristics of lower discharge over-potential, and improved electron transfer of its rate-determining step. The rate performance, operating voltage and discharge capacity are all improved.

Publication
Journal of The Electrochemical Society, 2019, 166(4), A641-A648

Supplementary files can be found here, including Additional Methods and Data.

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